N-(4-Chlorophenylsulfonyl)-2-methylpropanamide
نویسندگان
چکیده
In the crystal structure of the title compound, C(10)H(12)ClNO(3)S, the N-C bond in the C-SO(2)-NH-C segment has a gauche torsion with respect to the S=O bonds. The mol-ecule is twisted at the S atom with a C-S-N-C torsion angle of -62.3 (3)°. The benzene ring and the SO(2)-NH-CO-C segment form a dihedral angle of 89.3 (1)°. In the crystal, mol-ecules are linked by pairs of N-H⋯O hydrogen bonds into inversion dimers.
منابع مشابه
N-(2-Chlorophenylsulfonyl)-2-methylpropanamide
In the title compound, C(10)H(12)ClNO(3)S, the amide H atom is syn with respect to the ortho-chloro group in the benzene ring and the C-S-N-C torsion angle is 64.35 (16)°. The benzene ring and the SO(2)-NH-CO-C segment form a dihedral angle of 87.4 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds.
متن کامل2-Bromo-N-(4-chlorophenyl)-2-methylpropanamide
In the title mol-ecule, C(10)H(11)BrClNO, there is a twist between the mean plane of the amide group and the benzene ring [C(=O)-N-C-C torsion angle = -27.1 (3)°]. In the crystal, inter-molecular N-H⋯O and weak C-H⋯O hydrogen bonds link the mol-ecules into chains along [010].
متن کاملN,N′-Bis(4-chlorophenylsulfonyl)adipamide
In the title compound, C(18)H(18)Cl(2)N(2)O(6)S(2), the asymmetric unit contains half a mol-ecule with a center of symmetry at the mid-point of the central C-C bond. The dihedral angle between the benzene ring and the SO(2)-NH-C(O) segment in the two halves of the mol-ecule is 83.5 (2)°. In the crystal, N-H⋯O(S) inter-molecular hydrogen bonds link the mol-ecules into infinite chains running alo...
متن کاملN,N-Bis(4-chlorophenylsulfonyl)succinamide dihydrate
The asymmetric unit of the title compound, C(16)H(14)Cl(2)N(2)O(6)S(2)·2H(2)O, contains one half-mol-ecule of N,N-bis-(4-chloro-phenyl-sulfon-yl)succinamide, with a centre of symmetry at the mid-point of the central C-C bond, and one water mol-ecule. The succinamide mol-ecules are not directly connected via hydrogen bonds, but by hydrogen bonds via the water mol-ecules.
متن کاملN-(2-Chlorophenylsulfonyl)-2,2-dimethylpropanamide
In the title compound, C(11)H(14)ClNO(3)S, the C-S-N-C torsion angle is -61.69 (17)°. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds occur, generating R(2) (2)(8) loops.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011